Iodobenzene diacetate diacetoxy iodobenzene has a cas no 3240344 and has molecular formula c10h11io4. Free or benzofused 1,2,3triazoles 286 have been prepared by iodobenzene diacetate mediated oxidation of hydrazones 285 equation 37. Hypervalent iodineiii reagents in organic synthesis viktor v. Iodobenzene reacts readily with magnesium to form the grignard reagent, phenylmagnesium iodide. Diacetoxyiodobenzene 98%, c10h11io4, iodobenzene diacetate. Iodobenzene diacetate, iodobenzene diacetate 3240344. Iodobenzene 1,1diacetate 3240344 carbosynth product. There is no warranty of accuracy or completeness of any information contained herein. Xiajun wang yongqin he mengdan ren shengkang liu he liu guosheng huang. Covid19 is an emerging, rapidly evolving situation. Free or benzofused 1,2,3triazoles 286 have been prepared by iodobenzene diacetatemediated oxidation of hydrazones 285 equation 37. Leading manufacturer of diacetoxyiodobenzene cas no. To convert a reactant into the product, the initial step is to understand the chemical formula.
In a 3 or 5gallon stoneware crock are placed 950 ml 1 g. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. The mixture is agitated by a mechanical stirrer, and, as soon as the temperature drops. Hypervalent iodineiii reagents in organic synthesis. Diacetoxyiodobenzene pida was originally prepared by conrad willgerodt by reacting iodobenzene with a mixture of acetic acid and peracetic acid. This leads to the formation of an intermediate compound called benzenediazonium. Iodobenzene diacetates molecular formula is c10h11io4,the molecular weight is 322. Defect control in perovskite solar cells by interfacial. Volume 32, issue 51, 16 december 1991, pages 74937496. Iodobenzene diacetate suppliers, producers, cas no 324034. Iodobenzene diacetate, iodosobenzene, and diphenyliodonium salts act as ideal arylated sources in this reaction, producing bioactive aromatic. Structure, properties, spectra, suppliers and links for. Useful reagent for mild, rapid cleavage of 1,3dithianes to the parent. Both iodobenzene diacetate and camphorsulfonic acid are commercially accessible.
Chemical product and company identification product name. Lot and batch numbers can be found on a products label following the words lot or batch. Libr is an efficient catalyst for the dihydroxylation of alkenes to afford either syn or anti diols with excellent diastereoselectivity depending upon the use of naio 4 or phioac 2 as the oxidants. Predicted data is generated using the us environmental protection agencys episuite. Iodosobenzene diacetate, phenyliodonium diacetate, pida. H trifluoromethylation of quinolineamides on the c5 position with iodobenzene diacetate as the oxidizing agent. Methods and material for containment and cleaning up methods for cleaning up wear protective clothing as described in section 8 of this safety data sheet. Iodobenzene is used in various cc coupling reactions.
This page was last edited on 20 october 2018, at 02. Diacetoxyiodobenzene, also known as phenyliodineiii diacetate pida is a hypervalent iodine chemical with the formula c 6 h 5 iococh 3 2. Mar 01, 2006 read iodobenzene diacetate on alumina. An efficient method for synthesizing arylated heteroaromatics has been reported via pdcatalyzed ligand free crosscoupling of nheteroaromatic bromides with iodineiii reagents under mild conditions. All structured data from the file and property namespaces is available under the creative commons cc0 license. This information is stored within a cookie and setting this assumes acceptance. Material safety data sheet iodobenzene diacetate msds section 1. Greener organic syntheses under nontraditional conditions nopr. Accordingly, the chemical formula of aniline is and iodobenzene is to convert aniline to idobenzene, it is reacted with as catalyst this leads to the formation of an intermediate compound called benzenediazonium chloride. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided that echa is. Recyclable reagents and catalytic systems based on. Iodobenzene has a bimodal effect on the receptor cell tuned to benzoic acid ba of the female silk moth bombyx mori. Useful reagent for mild, rapid cleavage of 1,3dithianes to the parent carbonyl compounds.
Accordingly, the chemical formula of aniline is and iodobenzene is. Iodobenzene diacetate suppliers, producers, cas no 3240344. Iodobenzene diacetate, also known as periodinane, is a chemical compound containing hypervalent iodine and considered hypervalent. Seema finechem industry llp is manufacturer, exporter, supplier and producer of diacetoxyiodobenzene and other speciality chemical intermediates at most competitive price. In the typical condition, the three chemists used 1 or 2 mol% ph 3 pauots as the precatalyst and an oxidant formed in situ from iodobenzene diacetate and camphorsulfonic acid. To convert aniline to idobenzene, it is reacted with as catalyst. Seema finechem industry llp based in navi mumbai, india is a pioneer exporter, manufacturer and a major supplier of iodobenzene diacetate diacetoxyiodobenzene cas no. Buy high quality iodosobenzene diacetate 3240344 from carbosynth, your source for carbohydrates, nucleosides and fine chemicals. Diazonium salts in iodobenzene synthesis, hive novel discourse. Synthetic and mechanistic studies of catalytic oxidations by manganeseiii porphyrins and iodobenzene diacetate a capstone experiencethesis project presented in partial fulfillment of the requirements for the degree bachelor of science with honors college graduate distinction at western kentucky university by ka wai kwong. The addition of iodobenzene to the reaction mixture resulted in the formation of benzylamine. Numerous studies identify that chargecarrier nonradiative recombination of defects restrains the photovoltaic performance of the devices. Aurora ka6690 daib diacetoxyiodobenzene diacetoxyiodosobenzene iodine, bisacetatokophenyl iodobenzene diacetate iodobenzene i,i diacetate iodosobenzene diacetate iodosobenzene i,i diacetate labotestbb lt00847235 phenyliodine diacetate pia diacetoxyiodobenzen dihydroxyiodo.
A similar result was obtained when the reaction was performed with iodosobenzene, instead of iodobenzene diacetate. With stimulation by iodobenzene alone, a reduction of basic nerve impulse firing during exposure is followed by a transient poststimulus excitation rebound. An environmentally benign and solventfree synthesis of 3 aryl1,2,4triazolo4,3 a. It can be used in the preparation of iodobenzene dichloride, which is employed as an oxidant to oxidize alcohols to carbonyl compounds and as a chlorinating agent. Iodobenzene diacetate msds search our sds online database free. With the cas registry number 591504, it is also named as phenyliodonium. Distillation under reduced pressure gives 327335g 7476% of theory of iodobenzene, bp 7778c20 mm. F into complex e and the free iodosobenzene or iodobenzene diacetate.
Molecules free fulltext hypervalent iodinemediated ring. Diazonium salts in iodobenzene synthesis, hive novel. Phenylmagnesium iodide, like the bromide analog, is a synthetic equivalent for the phenyl anion synthon. A simple and efficient method has been developed for the oxidation of various heterocyclyl acylhydrazones 3 with iodobenzene diacetate ibd to heterocyclyl. Iodobenzene diacetate is one of the popular reagents of hypervalent iodine. Information provided on iodobenzene diacetate 3240344 is for reference only and is subject to change. Pdcatalyzed ligand free synthesis of arylated heteroaromatics by coupling of nheteroaromatic bromides with iodobenzene diacetate, iodosobenzene, or diphenyliodonium salts. Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Ungraded products supplied by tci america are generally suitable for common industrial uses or for research purposes but typically. The solvent was 2% methanol in chloroform, and most reactions were complete at room temperature between 20. H trifluoromethylation of quinolineamides on the c5 position with iodobenzene diacetate as the oxidizing agent zhaoyang wu state key laboratory of applied organic chemistry, key laboratory of nonferrous metal chemistry and resources utilization of gansu province, department of chemistry, lanzhou university, lanzhou, 730000. Cn101575293b method for preparing iodobenzene diacetate. Apollo scientific home products iodobenzene diacetate, tech. Green chemistry, organic synthesis, solventfree reactions, microwave irradiation, ultrasonic. Selective oxidations using aluminasupported iodobenzene diacetate under solvent free conditions.
The product could be isolated in about 8595 % yield, but this. The iodobenzene is an organic compound with the formula c 6 h 5 i. Diacetoxyiodobenzene, also known as phenyliodine iii diacetate pida is a hypervalent iodine chemical with the formula c. Apollo scientific currently provides pricing in several currencies. However, iodosobenzene diacetate alone oxidizes flavanones to flavones. Ibda is defined as iodobenzene diacetate very rarely. Zhdankin department of chemistry and biochemistry, university of minnesota duluth, duluth, minnesota 55812, usa email. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. The invention relates to a method for preparing iodobenzene diacetate, which comprises the following steps. Herein, a novel interfacial modifier iodobenzene diacetate daib is used to mitigate the defects and improve charge carrier transportation at the interface between the perovskite layer and hole transporting layer.
It is used as an oxidizing agent in organic chemistry. Iodobenzene reacts with chlorine to give the complex, iodobenzene dichloride, which is used as a solid source of chlorine. Diacetoxy iodobenzene iodobenzene diacetate cas no. Iodobenzene diacetate 3240344 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. Please select the one that is most appropriate for your business. The link is above is now fixed for direct downloading the pdf of the excellent article on the synthesis of iodobenzene novel easy preparations of some aromatic iodinei, iii, and v reagents, widely applied in modern organic synthesis. A simple and efficient method for the synthesis of novel pyrazolyl. Als environmental does not sell chemicals, but offers analytical lab testing to determine the presence of various elements and chemical compounds. Synthetic and mechanistic studies of catalytic oxidations. Iodobenzene 1,1 diacetate environmental precautions avoid discharge into drains or watercourses or onto the ground. Pdcatalyzed ligandfree synthesis of arylated heteroaromatics by. On the mechanism of action of cytochrome p450 journal of. Exposure to iodobenzene causes an inhibition of the response to ba.
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